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Transformations of cycloalkanes under the action of organoaluminum compounds and transition metal complexes in the presence of polychloromethanes

Research paper by R. A. Sadykov, M. G. Samokhina, U. M. Dzhemilev

Indexed on: 01 Jul '01Published on: 01 Jul '01Published in: Russian Chemical Bulletin



Abstract

A catalytic system comprising an organoaluminum compound, polychloromethane, and a transition metal complex transforms cyclohexane into dimethyldecalins, cyclooctane into dimethyl- and ethylcyclohexanes, and endo-tricyclo[5.2.1.02,6]decane into its exo-isomer under mild conditions.