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Synthesis and electrochemistry of double-decker buckyferrocenes.

Research paper by Yutaka Y Matsuo, Kazukuni K Tahara, Eiichi E Nakamura

Indexed on: 01 Jun '06Published on: 01 Jun '06Published in: Journal of the American Chemical Society



Abstract

D5d- and C5v-symmetric double-decker buckyferrocene Fe2(C60R10)Cp2 (R10 = Me5Ph5 and Me10) represents a new type of diiron complexes featuring conjugative connection of two ferrocene groups by a hoop-shaped [10]cyclophenacene. The compounds exhibit two-electron oxidation and two-electron reduction behavior, generating dicationic and dianionic species. The two iron atoms interact with each other through the pi-conjugation of the cyclophenacene, as revealed by differential pulse voltammetric analysis of the D5d Fe2(C60Me10)Cp2.