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Steam gasification of waste tyre: influence of process temperature on yield and product composition.

Research paper by Sabrina S Portofino, Antonio A Donatelli, Pierpaolo P Iovane, Carolina C Innella, Rocco R Civita, Maria M Martino, Domenico Antonio DA Matera, Antonio A Russo, Giacinto G Cornacchia, Sergio S Galvagno

Indexed on: 04 Jul '12Published on: 04 Jul '12Published in: Waste Management



Abstract

An experimental survey of waste tyre gasification with steam as oxidizing agent has been conducted in a continuous bench scale reactor, with the aim of studying the influence of the process temperature on the yield and the composition of the products; the tests have been performed at three different temperatures, in the range of 850-1000°C, holding all the other operational parameters (pressure, carrier gas flow, solid residence time). The experimental results show that the process seems promising in view of obtaining a good quality syngas, indicating that a higher temperature results in a higher syngas production (86 wt%) and a lower char yield, due to an enhancement of the solid-gas phase reactions with the temperature. Higher temperatures clearly result in higher hydrogen concentrations: the hydrogen content rapidly increases, attaining values higher than 65% v/v, while methane and ethylene gradually decrease over the range of the temperatures; carbon monoxide and dioxide instead, after an initial increase, show a nearly constant concentration at 1000°C. Furthermore, in regards to the elemental composition of the synthesis gas, as the temperature increases, the carbon content continuously decreases, while the oxygen content increases; the hydrogen, being the main component of the gas fraction and having a small atomic weight, is responsible for the progressive reduction of the gas density at higher temperature.