Self-standing nanofilms of polysulfone doped with sulfonated polysulfone via solvent evaporation for forward osmosis

Research paper by Hao-Ge Yuan, Yuan-Yuan Liu, Tian-Yin Liu, Xiao-Lin Wang

Indexed on: 11 Oct '16Published on: 21 Sep '16Published in: Journal of Membrane Science


A polysulfone (PSf) self-standing nanofilm was designed for forward osmosis (FO) via the solvent evaporation method and doping sulfonated polysulfone (SPSf) from 0 to 5 wt.% to tune the structure and surface property of the nanofilm. The separation performance of the nanofilm was investigated in hydraulic and osmotic pressure-driven processes. The experimental results showed that attributed to the formation of interconnected SPSf network in the PSf matrix, the pore size distribution of the PSf self-standing nanofilm narrowed down at the optimized SPSf content of 1 wt.%, above which SPSf aggregation occurred and the pore size distribution became broadened. Moreover, by doping SPSf, a more hydrophilic and negatively charged surface was obtained. At the SPSf content of 1 wt.%, the rejection of the nanofilm to Na2SO4 increased from 82.0% to 90.8% and the water flux was improved from 0.15 to 0.17 L m−2 h−1 in the pressure driven process. Correspondingly, the thinnest nanofilm with the thickness of 46 nm has a highest water flux of 46.4 L m−2 h−1 in the FO process using 1.25 mol L−1 Na2SO4 as the draw solution. Such a self-standing nanofilm provides a new approach to develop high performance FO membranes.

Graphical abstract 10.1016/j.memsci.2016.09.034.jpg
Figure 10.1016/j.memsci.2016.09.034.0.jpg
Figure 10.1016/j.memsci.2016.09.034.1.jpg
Figure 10.1016/j.memsci.2016.09.034.2.jpg
Figure 10.1016/j.memsci.2016.09.034.3.jpg
Figure 10.1016/j.memsci.2016.09.034.4.jpg
Figure 10.1016/j.memsci.2016.09.034.5.jpg
Figure 10.1016/j.memsci.2016.09.034.6.jpg