Self-assembly of magnetic Ni nanoparticles into 1D arrays with antiferromagnetic order.

Research paper by V V Bliznyuk, S S Singamaneni, S S Sahoo, S S Polisetty, Xi X He, Ch Ch Binek

Indexed on: 07 May '09Published on: 07 May '09Published in: Nanotechnology


In this paper, we report on the magnetic properties of isolated nanoparticles and interacting nanochains formed by the self-assembly of Ni nanoparticles. The magnetic properties were studied using superconducting quantum interference device (SQUID) magnetometry and magnetic force microscopy (MFM). We demonstrate that single-domain Ni nanoparticles spontaneously form one-dimensional (1D) chains under the influence of an external magnetic field. Furthermore, such magnetic field-driven self-assembly in conjunction with surface templating produces regular arrays of 1D nanochains with antiferromagnetic intra-chain order. The antiferromagnetic order, which is in striking contrast to what is found for non-interacting nanoparticle assemblies within the chains, can be evidenced from MFM and SQUID measurements.