Segregation growth of epitaxial graphene overlayers on Ni(111)

Research paper by Yang Yang, Qiang Fu, Wei Wei, Xinhe Bao

Indexed on: 07 Sep '16Published on: 07 Sep '16Published in: Science Bulletin


The orientation control of graphene overlayers on metal surface is an important issue which remains as a challenge in graphene growth on Ni surface. Here we have demonstrated that epitaxial graphene overlayers can be obtained by annealing a nickel carbide covered Ni(111) surface using in situ surface imaging techniques. Epitaxial graphene islands nucleate and grow via segregation of dissolved carbon atoms to the top surface at about 400 °C. This is in contrast to a mixture of epitaxial and non-epitaxial graphene domains grown directly on Ni(111) at 540 °C. The different growth behaviors are related to the nucleation dynamics which is controlled by local carbon densities in the near surface region.

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