Quantcast

Preparation of Propargylic Sulfinates and their [2,3]-Sigmatropic Rearrangement to Allenic Sulfones

Research paper by Rama Rao Tata, Carissa S. Hampton, Michael Harmata

Indexed on: 31 Jan '17Published on: 30 Jan '17Published in: Advanced Synthesis & Catalysis



Abstract

The scope of the [2,3]-sigmatropic rearrangement of propargylic sulfinates to allenic sulfones by silver catalysis was expanded. A series of new propargylic sulfinate esters was generated from a variety of aromatic and heteroaromatic sulfonyl chlorides and their rearrangement to allenic sulfones is reported. In addition, the synthesis of propargylic sulfinate esters containing electron-withdrawing benzenesulfonyl chlorides is reported.