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Nitrogen-containing organosilicon compounds

Research paper by É. Ya. Kukevits, V. A. Ignatova, I. F. Kovalev, L. I. Libert, M. G. Voronkov

Indexed on: 01 Nov '72Published on: 01 Nov '72Published in: Russian Chemical Bulletin



Abstract

The relative basicity of a series of alkoxy- and (aminoalkoxy)silanes was investigated by the method of IR spectroscopy.The influence of the inductive effect and pπ-dπ conjugation on the electronic donor properties of the oxygen and nitrogen atoms in the Si-O and Si-N bonds was discussed.The correlation functions between the shift of the IR band of the vibrations of the C-D bond of deuterochloroform and the integral intensity of the band of the N-H bond were established.