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Light-driven monodirectional molecular rotor.

Imported: 22 Apr '16 | Published: 18 Sep '99

N N Koumura, R W RW Zijlstra, R A RA van Delden, N N Harada, B L BL Feringa

Nature

Abstract: Attempts to fabricate mechanical devices on the molecular level have yielded analogues of rotors, gears, switches, shuttles, turnstiles and ratchets. Molecular motors, however, have not yet been made, even though they are common in biological systems. Rotary motion as such has been induced in interlocked systems and directly visualized for single molecules, but the controlled conversion of energy into unidirectional rotary motion has remained difficult to achieve. Here we report repetitive, monodirectional rotation around a central carbon-carbon double bond in a chiral, helical alkene, with each 360 degrees rotation involving four discrete isomerization steps activated by ultraviolet light or a change in the temperature of the... Read More

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