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Isotopec exchange study of elec trophilic substitution at a saturated carbon atom

Research paper by O. A. Reutov, V. I. Sokolov, I. P. Beletskaya

Indexed on: 01 Sep '61Published on: 01 Sep '61Published in: Russian Chemical Bulletin



Abstract

A study has been made of the kinetics of the isotope exchange of the ethyl ester of α-brommercuryphenylacetic acid with Hg*Br2 in DMF. It has been shown that the reaction proceeds with preliminary formation of the complex Hg*Br2 n DMF.The overall order of the reaction with these complexes, namely the second order, has been determined along with the constants in the Arrhenius equation.