High-efficiency in situ resonant inelastic x-ray scattering (iRIXS) endstation at the Advanced Light Source.

Research paper by Ruimin R Qiao, Qinghao Q Li, Zengqing Z Zhuo, Shawn S Sallis, Oliver O Fuchs, Monika M Blum, Lothar L Weinhardt, Clemens C Heske, John J Pepper, Michael M Jones, Adam A Brown, Adrian A Spucces, Ken K Chow, Brian B Smith, Per-Anders PA Glans, et al.

Indexed on: 05 Apr '17Published on: 05 Apr '17Published in: The Review of scientific instruments


An endstation with two high-efficiency soft x-ray spectrographs was developed at Beamline 8.0.1 of the Advanced Light Source, Lawrence Berkeley National Laboratory. The endstation is capable of performing soft x-ray absorption spectroscopy, emission spectroscopy, and, in particular, resonant inelastic soft x-ray scattering (RIXS). Two slit-less variable line-spacing grating spectrographs are installed at different detection geometries. The endstation covers the photon energy range from 80 to 1500 eV. For studying transition-metal oxides, the large detection energy window allows a simultaneous collection of x-ray emission spectra with energies ranging from the O K-edge to the Ni L-edge without moving any mechanical components. The record-high efficiency enables the recording of comprehensive two-dimensional RIXS maps with good statistics within a short acquisition time. By virtue of the large energy window and high throughput of the spectrographs, partial fluorescence yield and inverse partial fluorescence yield signals could be obtained for all transition metal L-edges including Mn. Moreover, the different geometries of these two spectrographs (parallel and perpendicular to the horizontal polarization of the beamline) provide contrasts in RIXS features with two different momentum transfers.