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Heteroadamantanes and their derivatives. 14. Synthesis of 3,6-diazahomoadamantan-9-ols and their acetates

Research paper by A. I. Kuznetsov, I. A. Vladimirova, T. M. Serova, A. S. Moskovkin

Indexed on: 01 Jun '91Published on: 01 Jun '91Published in: Chemistry of Heterocyclic Compounds



Abstract

The reduction of 3,6-diazahomoadamantan-9-ones with metal hydrides gave 3,6-diazahomoadamantan-9-ols, which were convened to acetates by the action of acetic anhydride. The effect of the substituents in the nodal positions on the rates of reduction and acylation is demonstrated.