Fast proton conduction path in {\text{Ni}} - {\text{BaCe}}_{{0.8}} {\text{Y}}_{{0.2}} {\text{O}}_{{2.9 - \delta }} membrane

Research paper by S.-J. Song, J.-H. Moon, H.-S. Park, S. E. Dorris, U. Balachandran

Indexed on: 02 Aug '07Published on: 02 Aug '07Published in: Ionics


The effect of metal-to-oxide grain boundary layer in \( {\text{Ni}} - {\text{BaCe}}_{{0.8}} {\text{Y}}_{{0.2}} {\text{O}}_{{3 - \delta }} \) (BCY) cermet membrane on hydrogen permeation was studied by applying the different size of oxide grain on Ni-BCY membranes. Two types of cermet membranes having different grain size of oxide were prepared by using different starting particle size of oxide powder. The hydrogen flux of coarse-oxide-grain membrane showed higher flux than that of small-oxide-grain membrane. It was understood that the negative potential at metal-to-oxide grain boundary, reference to the bulk oxide (\( \phi _{0} < \phi _{\infty } = 0 \)), was developed, and the accumulation of the effectively positively charged protons may occur at the grain boundary layer (space charge layer), which may result in providing highly conductive proton path by shifting the charge neutrality condition from \( {\left[ {OH^{ \bullet }_{O} } \right]} = {\left[ {Y^{/}_{{Ce}} } \right]} \) to \( {\left[ {OH^{ \bullet }_{O} } \right]} = n \).