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Dodigen 213-N as corrosion inhibitor for ASTM 1010 mild steel in 10% HCL

Research paper by M. F. L. Granero, P. H. L. S. Matai, I. V. Aoki, I. C. Guedes

Indexed on: 14 Feb '09Published on: 14 Feb '09Published in: Journal of Applied Electrochemistry



Abstract

This article describes a study of the behavior of a mixture of amines and amides, commercially known as Dodigen 213-N (D-213 N), as a corrosion inhibitor for ASTM 1010 mild steel in 10% w/w HCl solution. The concentration range used was 1 × 10−5 M to 8 × 10−4 M. The weight loss and electrochemical techniques used were corrosion potential measurement, anodic and cathodic polarization curves, and electrochemical impedance spectroscopy (EIS). The solution temperature was 50 ± 1 °C and it was naturally aerated. The corrosion potential values shifted to slightly more positive values, thus indicating mixed inhibitor behavior. The anodic and cathodic polarization curves showed that D-213 N is an effective corrosion inhibitor, since both the anodic and the cathodic reactions were polarized in comparison with those obtained without inhibitor. For all concentrations the cathodic polarization curves were more polarized than the anodic ones. The inhibition efficiency was in the range 75–98%, calculated from values of weight loss and corrosion current density, icorr, obtained by extrapolation of Tafel cathodic linear region.