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Direct Evidence of Lithium Ion Migration in Resistive Switching of Lithium Cobalt Oxide Nanobatteries.

Research paper by Van Son VS Nguyen, Van Huy VH Mai, Pascale P Auban Senzier, Claude C Pasquier, Kang K Wang, Marcelo J MJ Rozenberg, Nathalie N Brun, Katia K March, François F Jomard, John J Giapintzakis, Cristian N CN Mihailescu, Evripides E Kyriakides, Pavan P Nukala, Thomas T Maroutian, Guillaume G Agnus, et al.

Indexed on: 18 May '18Published on: 18 May '18Published in: Small



Abstract

Lithium cobalt oxide nanobatteries offer exciting prospects in the field of nonvolatile memories and neuromorphic circuits. However, the precise underlying resistive switching (RS) mechanism remains a matter of debate in two-terminal cells. Herein, intriguing results, obtained by secondary ion mass spectroscopy (SIMS) 3D imaging, clearly demonstrate that the RS mechanism corresponds to lithium migration toward the outside of the Li CoO layer. These observations are very well correlated with the observed insulator-to-metal transition of the oxide. Besides, smaller device area experimentally yields much faster switching kinetics, which is qualitatively well accounted for by a simple numerical simulation. Write/erase endurance is also highly improved with downscaling - much further than the present cycling life of usual lithium-ion batteries. Hence very attractive possibilities can be envisaged for this class of materials in nanoelectronics. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.