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Confirmation of the classic tris(2,2'-bipyridyl)ruthenium(II) and oxalate electrochemiluminescence mechanism using EPR spectroscopy.

Research paper by Christopher M CM Hindson, Paul S PS Francis, Graeme R GR Hanson, Neil W NW Barnett

Indexed on: 02 Jun '11Published on: 02 Jun '11Published in: Chemical Communications



Abstract

A chemically initiated adaptation of the classic [Ru(bipy)(3)](2+)/oxalate electrochemiluminescence coreactant system has revealed the elusive radical intermediates of the light-producing pathway. Oxalyl (HC(2)O(4)˙) and hydroxyformyl (HCO(2)˙) radicals have been captured on a quartz surface and characterised using EPR spectroscopy.