Chemically Filled and Au-Coupled BiSbS3 Nanorod Heterostructures for Photoelectrocatalysis

Research paper by Biplab K. Patra, Santimoy Khilari, Abhijit Bera, Shyamal K. Mehetor, Debabrata Pradhan, Narayan Pradhan

Indexed on: 25 Jan '17Published on: 11 Jan '17Published in: Chemistry of Materials


The synergistic effects of foreign ion incorporation into a semiconductor host crystal lattice can produce new functional properties. This concept has been adopted in the design of various energy materials for light harvesting, charge transport, and energy storage applications. Going beyond the traditionally used group II–VI and III–V semiconductor nanostructures, herein, 1D materials involving Bi(III) and Sb(III) sulfides are reported. Upon Sb dilution into the Bi2S3 lattice, exciting new material properties, including induction of localized surface plasmon resonance (LSPR) and a drastic change to the 1D crystal growth pattern, were observed. The presence of the Sb(III) precursor along with Bi(III) led to nanotubes with controlled length as the ultimate product, and their transformation to nanorods via chemical filling emerged as a new fundamental mechanism of crystal growth. Due to its slow thermal decomposition rate, the Sb(III) precursor dominantly filled these tubes, resulting in graded alloy Bi1.09Sb0.91S3 (BAS) nanorods. Further, by coupling with Au via seeded nucleation, Au–Bi1.09Sb0.91S3 (Au-BAS) 1D heteronanostructures were designed, in which Au remained at the center of the BAS nanorods. On the basis of these advantages, these nanostructures were employed for photoelectrocatalytic (PEC) water splitting, and significant enhancement was observed in the Au-coupled rods.

Figure 10.1021/acs.chemmater.6b04266.1.jpg
Figure 10.1021/acs.chemmater.6b04266.2.jpg
Figure 10.1021/acs.chemmater.6b04266.3.jpg
Figure 10.1021/acs.chemmater.6b04266.4.jpg
Figure 10.1021/acs.chemmater.6b04266.5.jpg
Figure 10.1021/acs.chemmater.6b04266.6.jpg
Figure 10.1021/acs.chemmater.6b04266.7.jpg
Figure 10.1021/acs.chemmater.6b04266.8.jpg
Figure 10.1021/acs.chemmater.6b04266.9.jpg
Figure 10.1021/acs.chemmater.6b04266.10.jpg