Chelation-assisted hydroesterification of alkenes catalyzed by rhodium complex.

Research paper by Kazuhiko K Yokota, Hiroto H Tatamidani, Yoshiya Y Fukumoto, Naoto N Chatani

Indexed on: 07 Nov '03Published on: 07 Nov '03Published in: Organic Letters

Abstract

[reaction: see text] The hydroesterification of alkenes with 2-pyridylmethanol (1) catalyzed by Rh(4)(CO)(12) is described. The reaction is accelerated by the presence of a pyridine ring in the alcohol 1. The reaction is applicable to various alkenes, both terminal and internal alkenes.

Chelation-assisted hydroesterification of alkenes catalyzed by rhodium complex.

Abstract

More like this:

Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2.

Domino C-F Bond Activation of the CF3 Group: Synthesis of Fluorinated Dibenzo[a,c][7]annulenes from 2-(Trifluoromethyl)-1-alkenes and 2,2'-Diceriobiaryls.

Cs2CO3-Mediated Regio- and Stereoselective Sulfonylation of 1,1-Dibromo-1-alkenes with Sodium Sulfinates

Chelation-assisted hydroesterification of alkenes catalyzed by rhodium complex.

Abstract

More like this:

Highly selective synthesis of (E)-3-methyl-1-trialkylsilyl-3-en-1-ynes via trans-selective alkynylation catalyzed by Cl2Pd(DPEphos) and stereospecific methylation with methylzincs catalyzed by Pd(tBu3P)2.

Domino C-F Bond Activation of the CF3 Group: Synthesis of Fluorinated Dibenzo[a,c][7]annulenes from 2-(Trifluoromethyl)-1-alkenes and 2,2'-Diceriobiaryls.

Cs2CO3-Mediated Regio- and Stereoselective Sulfonylation of 1,1-Dibromo-1-alkenes with Sodium Sulfinates

This website uses cookies